16. Answer is "D".
20. Answer is "A - Bismuth".
In transistors, applying an impurity to a pure element to enhance the conductivity is called doping.
There are two types of doping as n-doping and p-doping.
n-doping -
Impurity has more valence electrons than the element of semiconductor. Example is silicon (4 valence electrons) with phosphorus (impurity with 5 valence electrons)
p-doping -
Impurity has less number of valence electrons than the element of semiconductor. Example is Si (4 valence electrons) with B (3 valence electron impurity).
Here, germanium has 6 valence electrons. To emit free electrons, germanium should combine with substance which has less number of valence electrons as bismuth (5 valence electrons).