When 9.72 g of an unknown non-electrolyte is dissolved in 50.0 g of cyclohexane, the boiling point increased to 84.93 degrees C from 80.7 degrees C. If the Kbp of the solvent is 2.79 K/m, calculate the molar mass of the unknown solute.

Respuesta :

Answer : The molar mass of unknown compound is 128.22 g/mole

Explanation :

Mass of unknown compound = 9.72 g

Mass of solvent = 50.0 g

Formula used :

[tex]\Delta T_b=i\times K_b\times m\\\\T_2-T_1=i\times K_b\times\frac{\text{Mass of unknown compound}}{\text{Molar mass of unknown compound}\times \text{Mass of solvent in Kg}}[/tex]

where,

[tex]\Delta T_b[/tex] = elevation in boiling point

[tex]T_1[/tex] = temperature of solvent = [tex]80.7^oC=273+80.7=353.7K[/tex]

[tex]T_2[/tex] = temperature of solution = [tex]84.93^oC=273+84.93=357.93K[/tex]

i = Van't Hoff factor = 1 (for non-electrolyte)

[tex]K_f[/tex] = boiling point constant for solvent = 2.79 K/m

m = molality

Now put all the given values in this formula, we get:

[tex](357.93-353.7)K=1\times (2.79K/m)\times \frac{9.72g\times 1000}{\text{Molar mass of unknown compound}\times 50.0g}[/tex]

[tex]\text{Molar mass of unknown compound}=128.22g/mole[/tex]

Therefore, the molar mass of unknown compound is 128.22 g/mole