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A concentration cell is constructed using two Ni electrodes with Ni2+ concentrations of 1.0 M and 1.00 � 10�4 M in the two half-cells. The reduction potential of Ni2+ is �0.23 V. Calculate the potential of the cell at 25�C if the more dilute Ni2+ solution is in the anode compartment.

Respuesta :

Answer: The cell potential of the cell is +0.118 V

Explanation:

The half reactions for the cell is:

Oxidation half reaction (anode):  [tex]Ni(s)\rightarrow Ni^{2+}+2e^-[/tex]

Reduction half reaction (cathode):  [tex]Ni^{2+}+2e^-\rightarrow Ni(s)[/tex]

In this case, the cathode and anode both are same. So, [tex]E^o_{cell}[/tex] will be equal to zero.

To calculate cell potential of the cell, we use the equation given by Nernst, which is:

[tex]E_{cell}=E^o_{cell}-\frac{0.0592}{n}\log \frac{[Ni^{2+}_{diluted}]}{[Ni^{2+}_{concentrated}]}[/tex]

where,

n = number of electrons in oxidation-reduction reaction = 2

[tex]E_{cell}[/tex] = ?

[tex][Ni^{2+}_{diluted}][/tex] = [tex]1.00\times 10^{-4}M[/tex]

[tex][Ni^{2+}_{concentrated}][/tex] = 1.0 M

Putting values in above equation, we get:

[tex]E_{cell}=0-\frac{0.0592}{2}\log \frac{1.00\times 10^{-4}M}{1.0M}[/tex]

[tex]E_{cell}=0.118V[/tex]

Hence, the cell potential of the cell is +0.118 V

The  cell potential for the cell as calculated  is 0.118 V.

What is the Nernst equation?

The Nernst equation can be used to obtain the cell potential of a cell under non- standard conditions. The standard cell potential in this case is zero owing to the fact that both cathode and anode are made of nickel.

Hence;

Ecell = E°cell - 0.0592/nlog Q

Ecell = 0 - 0.0592/2 log (1 00 * 10^-4/1)

Ecell = 0.118 V

The  cell potential for the cell as calculated  is 0.118 V.

Learn more about Nernst equation: https://brainly.com/question/721749