A galvanic (voltaic) cell consists of an electrode composed of magnesium in a 1.0 M magnesium ion solution and another electrode composed of silver in a 1.0 M silver ion solution, connected by a salt bridge. Calculate the standard potential for this cell at 25 °C. Standard reduction potentials can be found here.

Respuesta :

Answer: The standard potential of the cell is 3.17 V

Explanation:

The substance having highest positive [tex]E^o[/tex] potential will always get reduced and will undergo reduction reaction.

The half reactions for the cell is:  

Oxidation half reaction (anode):  [tex]Mg(s)\rightarrow Mg^{2+}+2e^-;E^o_{Mg^{2+}/Mg}=-2.37V[/tex]

Reduction half reaction (cathode):  [tex]Ag^{+}+e^-\rightarrow Ag(s);E^o_{Ag^+/Ag}=+0.80V[/tex]

Substance getting oxidized always act as anode and the one getting reduced always act as cathode.

To calculate the [tex]E^o_{cell}[/tex] of the reaction, we use the equation:

[tex]E^o_{cell}=E^o_{cathode}-E^o_{anode}[/tex]

Putting values in above equation, we get:

[tex]E^o_{cell}=0.80-(-2.37)=3.17V[/tex]

Hence, the standard potential of the cell is 3.17 V