Consider the following reaction:
NH4HS(s)⇌NH3(g)+H2S(g)
An equilibrium mixture of this reaction at a certain temperature was found to have [NH3]= 0.276 M and [H2S]= 0.370 M.What is the value of the equilibrium constant (Kc) at this temperature?

Respuesta :

Answer:

Kc = 0.102

Explanation:

NH₄HS (s) ⇌ NH₃ (g) + H₂S (g)

The equilibrium constant for the above reaction , can be written as the product of the concentration of product raised to the power of stoichiometric coefficients in a balanced equation of dissociation divided by the product of the concentration of reactant raised to the power of stoichiometric coefficients in the balanced equation of dissociation .

Hence ,

Kc = [ NH₃ (g) ][ H₂S (g) ] / [ NH₄HS (s) ]

Since, the state of NH₄HS  is solid so, it's concentration will remain constant , hence , the equation can be rearranged as -  

Kc = [ NH₃ (g) ][ H₂S (g) ]

From the question ,

[ NH₃ (g) ] = 0.276 M

[ H2S (g) ] = 0.370 M

Now, putting it in the above equation ,

Kc = [ NH₃ (g) ][ H₂S (g) ]

Kc = 0.276  *  0.370  

Kc = 0.102