Answer:Statement 1 and 3 are true
Explanation:
Ca+(g) + e- ➡Ca(g)
Electron affinity of an atom or molecule is defined as the change in energy (in kJ/mole) of a neutral molecule(in gaseous state)when an electron is added to an atom to form a negative ion.Energy is released in the process thus the first electron affinities are negative.
On the other hand ionisation energy is the quantity of an energy a gaseous atom in its ground must absorb to discharge an electron.
H(g)➡H+(g) + e-
Considering both these definitions,statement 1 and 3 both falls true.