1. A solution is made by mixing 50mL of 2.0M K2HPO4 and 25mL of 2.0M KH2PO4. The solution is diluted to a final volume of 200mL. what is the pH of the final solution

Respuesta :

Answer:

The pH of the final solution is 7.15

Explanation:

50 mL of 2.0 M of [tex]K_2HPO_4[/tex] and 25 mL of 2.0 M of [tex]KH_2PO_4[/tex] were mixed to make a solution

Final volume of the solution after dilution = 200 mL

Final concentration of [tex]K_2HPO_4, [K_2HPO_4] = \frac{50 mL\times 2 M}{200 mL} = 0.5 M[/tex]

Final concentration of[tex]KH_2PO_4, [KH_2PO_4] = \frac{25 mL\times 2 M}{200 mL} = 0.25 M[/tex]

We use Hasselbach- Henderson equation:

[tex]pH = pK_a+ log \frac{[salt]}{[acid]}pka of KH_2PO_4 = 6.85[/tex]

Substituting the values:

[tex]pH = 6.85+ log \frac{0.5}{0.25}pH = 6.85+ log 2pH = 6.85+ 0.3 = 7.15[/tex]

Therfore,  the pH of the final solution is 7.15