Respuesta :
Answer:
ΔG° = 80 Kj/mole
Explanation:
ΔG° = -R·T·ln(Kw)
R = 0.008314 Kj/mol·K
T = 25°C = 298K
Kw = 1 x 10⁻¹⁴
ΔG° = -R·T·ln(Kw) -(0.08314Kj/mol·K)(298K)ln(1 x 10⁻¹⁴)
= -(0.008314)(298)(-32.2)Kj/mole
= 79.78Kj/mole ≈ 80Kj/mole (1 sig.-fig.)
The change in free energy for the autoionization of water at 25°C is -79.9 KJ
Using the formula;
ΔG = -RTlnK
ΔG = change in free energy = ?
R = gas constant = 8.314 J/K/mol
T = temperature = 298 K
K = equilibrium constant = 1.0 X 10^-14
Substituting into the given formula as;
ΔG = - (8.314 J/K/mol × 298 K × ln(1.0 X 10^-14))
ΔG = -7.99 × 10^4 J/mol or -79.9 KJ/mol
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