For a reaction: aA → Products, [A]o -4.3 M, and the first two half-lives are 56 and 28 minutes, respectively. Calculate k (without units). Show Work!

A. 7.7 x 10^-2
B. 4.2 x 10^-3
C. 3.8 x 10^-2
D. 8.3 x 10^-3
E. None of these​

Respuesta :

Answer:

C.[tex]3.8\times 10^{-2}[/tex]

Explanation:

We are given that

Initial concentration, [tex][A]_o=4.3 M[/tex]

First half life, [tex]t_{\frac{1}{2}}=56[/tex]minutes

Second half life, [tex]t'_{\frac{1}{2}}=28[/tex]minutes

We have to find K.

The given reaction is zero order reaction.

We know that for zero order reaction

[tex]t_{\frac{1}{2}}=\frac{[A]_o}{2k}[/tex]

Using the formula

[tex]56=\frac{4.3}{2k}[/tex]

[tex]k=\frac{4.3}{2\times 56}[/tex]

[tex]k=3.8\times 10^{-2}[/tex]

Hence, option C is correct.

Zero-order reactions are the reactions when a surface or a catalyst is required for the reaction to proceed and is saturated by the reactant chemicals. The result of the concentration versus the time plot will be a straight line in a zero-order reaction.

[tex]3.8 \times 10 ^{-2}[/tex] is the value of k.

How to calculate the value of k?

Given,

  • Initial concentration [tex][A_{0}][/tex] = 4.3 M
  • The first half-life of the reactant [tex](t \dfrac{1}{2})[/tex] = 56 minutes
  • The second half-life of the reactant [tex](t \dfrac{1}{2})[/tex]  = 28 minutes

The given reaction in the question is of zero-order and for that, we know that,

[tex]t \dfrac{1}{2} = \dfrac{[A_{0}] }{2\;\rm k}[/tex]

Substituting the values in the equation we get:

[tex]\begin{aligned}56 &= \dfrac{4.3 }{2\; \rm k}\\\\\rm k &= {4.3 }{2 \times 56}\\\\\rm k &= 3.8 \times 10^{ -2}\end{aligned}[/tex]

Therefore, option C is correct.

Learn more about the zero-order reaction here:

https://brainly.com/question/4638382