What is the pH of a buffer system that contains 0.200 M hydrocyanic acid (HCN) and 0.190 M sodium cyanide (NaCN)? The pKa of hydrocyanic acid is 9.31.

Respuesta :

pH=pKa + log [salt] / [acid] = 9.31 + log 0.15 / 0.20 = 9.31 - 0.125 pH = 9.19

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The pH of the buffer system that contains 0.2 M hydrocyanic acid (HCN) and 0.190 M sodium cyanide (NaCN) is 9.29

From the question given above, the following data were obtained:

pKa of HCN = 9.31

Concentration of HCN, [HCN] = 0.2 M

Concentration of NaCN, [NaCN] = 0.190 M

pH =?

The pH of the buffer system can obtain by using the Henderson-Hasselbach equation as illustrated below:

pH = pKa + log [salt] / [acid]

pH = pKa+ log [NaCN] / [HCN]

pH = 9.31 + log (0.190/ 0.2)

pH = 9.29

Therefore, the pH of the buffer system is 9.29

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