N2 is a homonuclear molecule and NO+ is a heteronuclear molecular ion hence the MO structure of NO+ different than that of N2.
The molecular orbital is formed by the combination of atomic orbitals. We should note that the number of molecular orbitals must be equal to the number of combining atomic orbitals.
Now we know that N2 is a homonuclear molecule and NO+ is a heteronuclear molecular ion hence the MO structure of NO+ different than that of N2.
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