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The only compound which does not undergo direct Friedel crafts alkylation is Nitrobenzene. This is because the nitro group present in the nitrobenzene is actively electron withdrawn, it is also known to deactivate the ring present in the atom.

What do you mean by Friedel crafts alkylation?

Friedel-Crafts Alkylation is the process of adding an alkyl group in place of an aromatic proton. This is accomplished by using a carbocation to conduct an electrophilic assault on the aromatic ring. Alkyl halides are used as reactants in the Friedel-Crafts alkylation process, which produces alkylbenzenes. The formation of C-C bonds and the activation of C-H are two of organic chemistry's most crucial applications of Friedel-Crafts reactions. By joining an alkyl group to an arene molecule, Friedel-Crafts-style alkylations serve as the building blocks for the production of a wide variety of industrial goods.

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