A chemist titrates of a pyridine solution with solution at . Calculate the pH at equivalence. The of pyridine is .Round your answer to decimal places.Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of solution added.

Respuesta :

pH = 2.96, for the given situation.

C5H5N + HBr --------------> C5H5N+  + Br-

millimoles of pyridine = 80 x 0.3184 =25.472mM

25.472 millimoles of HBr must be added to reach equivalence point.

25.472  = V x 0.5397

V =25.472/0.5397= 47.197 mL HBr

total volume = 80 + 47.197= 127.196 mL

Concentration of [C5H5N+] = no of moles / volume=

25.472/ 127.196= 0.20M

so,

pOH = 1/2 [pKw + pKa + log C]

pKb = 8.77

pOH = 1/2 [14 + 8.77 + log 0.20]

pOH = 11.0355

pH = 14 - 11.0355

pH = 2.96

What is pH ?

A substance's pH level indicates how basic or acidic it is. pH ranges from 0 to 14. The material is considered basic if its pH is higher than 7. The term "acidic" refers to a material with a pH below 7. The material is considered neutral when the pH value is exactly 7.

Anything that is capable of releasing a proton qualifies as acidic. A proton will accept a basic material. Visit this article to learn more about acids and bases.

The pH equation is:

([H+]) = -log pH

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