Acetone enolate preferentially attack the benzaldehyde rather than another acetone molecule because it is a strong nucleophile which will attack the carbonyl of benzaldehyde and forms a B- carbonyl alkoxide ion.
Benzalacetone is the end product of the aldol condensation reaction between acetone and benzaldehyde. Acetone may be deprotonated to produce a nucleophilic enolate anion since it contains -hydrogens (on both sides). Because it is significantly more electrophilic than a ketone, the aldehyde carbonyl interacts with the enolate quickly. Since it dehydrates spontaneously under the reaction conditions, the original aldol adduct cannot be separated. However, the resulting, - α, β-unsaturated ketone contains active hydrogen that can condense with additional benzaldehyde molecules.
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