The formula of Ammonium nitrate is (NH4)(NO3).
The decomposition of ammonium nitrate is shown in the following reaction:
(NH4)(NO3) ---> N2O + 2H2O
To calculate for the standard heat of ammonium nitrate, add the enthalpies of formation of the products, (N2O, H2O)
delta H = H_N2O + 2*(H_H2O)
The enthalpy of formation table can be found in several reference books, like Perry's Chemical Engineering Handbook or Thermodynamics books.