Assume that 30.0 mL of a 0.10 M solution of a weak base B that accepts one proton is titrated with a 0.10 M solution of a monoprotic strong acid HX. (a) How many moles of HX have been added at the equivalence point? (b) What is the predominant form of B at the equivalence point? (c) What factor determines the pH at the equivalence point? (d) Which indicator, phenolphthalein or methyl red, is likely to be the better choice for this titration?

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Please see attachment for the answers. I simply collated all data and explanation that I found. I hope it helps.
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a. The number of moles of HX that is added at the equivalence point is 0.0003 moles.

b. The predominant form of B at the equivalence point is [tex]BH^{+}[/tex]

c. A factor which determines the pH at the equivalence point is the acid-base nature of the conjugate base and acid respectively.

d. Methyl red is likely to be the better choice for this titration because it would change color in the acid range.

Given the following data:

  • Volume of weak base B = 30.0 mL.
  • Molarity of weak base B = 0.10 M.
  • Molarity of strong acid HX = 0.10 M.

What is an equivalence point?

An equivalence point can be defined as the point in a titration wherein the amount of reagent (titrant) added sufficiently neutralizes the analyte (titrand) solution. Thus, it is the amount of strong acid that is needed to neutralize a weak base completely

For this chemical reaction, the properly balanced chemical equation is written as follows:

                      [tex]B(aq)+HX(aq) \rightarrow BH^{+}(aq) + X^{-}(aq)[/tex]

By stoichiometry:

0.10 M solution = 0.10 moles of solute per liter of solution.

Note: 10,000 mL = 1 Liter.

[tex]Number\;of\;moles = \frac{30}{10000} \times 0.10\\\\Number\;of\;moles = 0.003 \times 0.10[/tex]

Number of moles = 0.0003 moles of HX.

b. The predominant form of B at the equivalence point is given by this equilibrium expression:

                                 [tex]B(aq)+HX(aq)\rightleftharpoons BH^{+} + X^{-}[/tex]

Therefore, the predominant form of B at the equivalence point is [tex]BH^{+}[/tex]

c. A factor which determines the pH at the equivalence point is the acid-base nature of the conjugate base and acid respectively.

d. Methyl red is likely to be the better choice for this titration because it would change color in the acid range.

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