Hello!
The dissociation reaction for Benzoic Acid is the following:
C₆H₅COOH + H₂O ⇄ C₆H₅COO⁻ + H₃O⁺
The Ka expression is the following and we clear for the concentration of H₃O⁺(X) assuming that the dissociation is little so we can rule it out in the denominator of the equation:
[tex]Ka= \frac{[C_6H_5COO^{-}]*[H_3O^{+}] }{[C_6H_5COOH]}=\frac{X*X }{0,40 -X} (assume: 0,40-X\approx0,40)\\ \\ X= \sqrt{0,40*6,50*10^{-5} }=0.00510M \\ \\ pH=-log([H_3O^{+}]=2,29 [/tex]
So, the pH of this Benzoic Acid solution is 2,29
Have a nice day!