Molality is defined as the number of moles of solute dissolved in 1 kg of solvent.
To calculate molality, we need to calculate the number of moles of CaCl₂.
Mass of CaCl₂ - 5.0 g
Molar mass of CaCl₂ - 111 g/mol
The number of moles of CaCl₂ - 5.0 g / 111 g/mol = 0.045 mol
we need to then calculate the number of moles in 1 kg solvent.
number of CaCl₂ moles in 500 g water - 0.045 mol
Therefore number of moles in 1 kg water - 0.045 mol / 500g x 1000 g = 0.090 mol
Molality of CaCl₂ - 0.090 mol/kg