An electrochemical cell has the following standard cell notation.

Mg(s) | Mg^2+ (aq) || Aq^+(aq) | Aq(s)

What is the standard potential for the cell?

Is this a spontaneous or non spontaneous reaction? Explain your answer.

Is this a galvanic cell or an electrolytic cell? Explain your answer.

Respuesta :

The cell notation is:

[tex]Mg(s)|Mg^{+2}(aq)||Ag^{+}(aq)|Ag(s)[/tex]

here in cell notation the left side represent the anodic half cell where right side represents the cathodic half cell

in anodic half cell : oxidation takes place [loss of electrons]

in cathodic half cell: reduction takes place [gain of electrons]

1) this is a galvanic cell

2) the standard potential of cell will be obtained by subtracting the standard reduction potential of anode from cathode

[tex]E^{0}_{Mg}=-2.38V[/tex]

[tex]E^{0}_{Ag}=+0.80V[/tex]

Therefore

[tex]E^{0}_{cell}=0.80-(-2.38)=+3.18V[/tex]

3) as the value of emf is positive the reaction will be spontaneous as the free energy change of reaction will be negative

Δ[tex]G^{0}=-nFE^{0}[/tex]

As reaction is spontaneous and there will be conversion of chemical energy to electrical energy it is a galvanic cell.